Nylon material

A study suggests that the global nylon market will rise to $34.4 billion by 2025. Nylon is a synthetic material. It has roles in various industries. It is specifically used in plastic molding industries. We use nylon in almost everything from the automotive industry to industrial equipment. The demand for nylon is rising day by day. So let’s talk about the properties and manufacturing process of nylon. We will also shed light on the most commonly asked question. Is nylon safe?

What is Nylon?

Nylon is a thermoplastic. It was discovered in the 1930s. It contains repeating units connected by amide bonds. It was made entirely from petrochemicals. So, we can melt it and convert it into fibers, films, and shapes. We can also mix nylon polymers with different additives. In this way, we can form different types of nylons. Each type of nylon has different properties based on its composition. Nylon polyamide 6, Nylon 12 (PA12), and Nylon 66 (PA 66) are the most common types of nylons used in the plastic industry. Moreover, they are also used in medical equipment and industrial machinery.

Nolon machining parts

Main Types Of Nylon Polymers

Here are the three main types of nylon polymers used in the plastic industry:

1. Nylon 6 (PA6)

Nylon 6 is also known as polycaprolactam. It is the most popular type of nylon. It is produced through ring-opening polymerization of caprolactam. Nylon 6 has a high melting point and excellent mechanical properties. It is often used in automotive parts and electrical components. Go to nylon injection molding page to know more.

2. Nylon 6,6 (PA66)

Nylon 6,6 is also known as polyhexamethylene adipamide. It is produced through the condensation polymerization of adipic acid and hexamethylenediamine. Nylon 6,6 has high stiffness. Moreover, it is resistant to abrasion and chemicals. It is mostly used in gears, bearings, and conveyor belts.

3. Nylon 12 (PA12)

Nylon 12 is also known as polydodecanamide. It has a lower melting point. Additionally, it has higher flexibility than nylon 6 and nylon 6,6. It is produced through the ring-opening polymerization of laurolactam. Nylon 12 has minimal distortion. It is resistant to chemicals. So, it is often used in fuel tanks and fuel lines. We can also use it in grommets and connectors.

Is Nylon safe

We mostly use these three types of nylons in the plastic industry. They can be processed using various methods including injection molding and extrusion.

Manufacturing of Nylon Plastic

You are now familiar with different nylon forms. So, let’s talk about its manufacturing process. Nylon production starts through a multi-step process. It starts with the production of monomers adipic acid and hexamethylenediamine. These are then combined in a reaction vessel. They are then heated to a high temperature of 280°C.  As a result, nylon salt is produced. We then convert this salt into a polymer through polycondensation.

After that, a long-chain polymer is formed and cut into small pellets. The pellets are then washed and dried. They are cooled and cut into chips. Different catalysts and conditions are used throughout the process to produce different types of nylon. Nylon is a tough and durable material. However, its production can release certain chemicals that may harm the environment.

Role of Nylon in the Plastic mold industry

Nylon plays a significant role in plastic mold industries. It is used to create molds for plastic injection molding. We can also use nylon for prototyping. So, it allows engineers to test and refine their designs. Nylon has a low friction coefficient. This makes it suitable for components like slides and ejector pins. Moreover, nylon is resistant to chemicals. Thus, it is suitable for use in molds that are exposed to harsh environments. Nylon is a tough material. As a result, it is ideal for creating wear-resistant parts such as gears.

Properties of Nylon Plastic

Here are the mechanical, chemical, and thermal properties of Nylon plastic.

1. Mechanical Properties

  • Tensile Strength: This material is super tough and intended for gear applications and fasteners that require mechanical strength.
  • Elasticity: Good elasticity enables it to regain its original size or shape after swelling or shrinking.
  • Impact Resistance: This makes it ideal in applications that have shocks as it offers excellent impact resistance.

2. Thermal Properties

  • Heat Resistance: Retains admixture properties at higher temperatures, beneficial to automotive as well as electric apparatuses.
  • Melting Point: Capability to withstand high temperature: The products achieve a high melting point, or range between 220 – 270 C.

3. Chemical Resistance

  • Resistance to Oils and Solvents: This material is quite resistant to many chemicals good for automotive and industrial applications.
  • Hydrolysis Resistance: Readily hydrolyzed particularly in humid environments or at high temperatures.

4. Electrical Properties

  • Insulation Qualities: Good electrical insulator that finds uses in electrical equipment.
  • Dielectric Strength: Compliant with electrical stress to provide security in electrical usage.

Is Nylon Safe? Safety Aspects

Now let’s return to the question asked in the beginning: is nylon safe? It is generally considered safe. Here are the safety aspects of nylon polymer

1. Nylon for Mold Production

Nylon plays a vital role in plastic mold production. It doesn’t release toxic fumes or chemical reactions during processing. It is suggested that nylon must be used with non-toxic mold coatings. It minimizes the risk of contamination

2. Safe for Food Contact

Nylon plastic is approved for food contact applications. We use it in kitchen appliances, utensils, and packaging. Furthermore, nylon ensures that it does not leach harmful chemicals into food or water. So nylon is safe for food contact

3. Non-toxic

We can say that nylon is a synthetic polymer that is generally regarded as safe to use on consumer products as it is non-toxic. It does not emit toxic fumes under ordinary use and is non-toxic to humans and the environment. It is so used for products such as textiles ( nylon dresses, ropes, etc), consumable products (Toothbrushes, hair combs, etc), and industrial products (gears, bushings, etc). So, nylon is generally inert. It does not release harmful chemicals. So, it does not have any adverse effects environment. Thus, humans can easily handle nylon plastic.

You can go to is tpe safe? Is silicone safe? is ABS plastic safe? and Is TPU safe to know more about other materials.

Nylon machining

4. Durable and Stable

Nylon is characterized by its impact strength, dimensional stability, high tensile strength, abrasion, and chemical resistance. Such properties mean that it will not degrade, or become dangerous or incapacitated beyond its intended purpose after being used for a long time. It can also become dangerous if exposed to adverse conditions. Moreover, it also resonates a high degree of stability to the structure. So, it does not degrade into other dangerous chemical components, which is important for long-term use.

5. FDA Approval

The U. S. Food and Drug Administration (FDA) has listed some nylon and its family as the food grade item. This approval is arrived from the fact that the product has to undergo substantial testing. So, we can check that the nylon does not contaminate food or beverages with some poisonous chemicals. Therefore, nylon finds its way into such products as; food packing materials, kitchenware, and equipment for food processing.

6. Medical Uses

In the medical industry, it is used in applications such as suture material, catheters, and implantable products among others. The nylon applied herein has bio competence. So, it can be used within the human body to improve upon the current situation. Moreover, it has an inability of bacteria to grow on it, and can easily be sterilized the material. So, it is safe for use in treating patients.

Potential risks associated with Nylon Polymer

We have discussed the safety aspects of nylon polymer in the previous section. So now let’s explain about the potential risks associated with it.

1. Nylon Polymer Impact on Human Health:

Different chemicals used in nylon production are adipic acid, hexamethylene, diammine, and caprolactam. These materials can cause skin and eye irritation. They can also cause digestive issues. Additionally, people handling it are prone to cancer and neurological disorders.

Nylon polymer is flammable. So, It can melt on exposure to extreme temperatures and cause skin issues. It can also trigger rashes and redness of the skin. So, it is suggested to keep it away from flames.

Moreover, precautionary measures are advised to minimize the damage. Workers handling these chemicals should wear personal protective equipment. In this way, we can ensure the safety of nylon.

2. Nylon Impact on the Environment

The development of the nylon industry is accompanied by high energy consumption and pollution issues. Nylon originates from non-renewable petroleum resources. It is produced in an energy-intensive manner. It requires large amounts of water to cool the fibers. It has a significant carbon footprint, and the washing process releases microplastic fibers that often end up in landfills. These are typically non-biodegradable at the end of their lifecycle. This means nylon products can persist in the environment for many years, especially in oceans and landfills. It significantly contributes to the plastic pollution problem.

We have discussed nylon’s Impact on the terrestrial environment. Now let’s talk about its role in the aquatic environment. substantial amounts of nylon are produced in countries with poor environmental laws. Its production requires a large quantity of water. So, water insecurity may rise in water-scarce areas. Nylon is a plastic-based substance. So, it does not degrade in the environment. Ocean microplastic contamination is drastically rising. This is because of the breakdown of nylon products such as fishing nets, ropes, and packaging materials. Hence, it can harm aquatic life and contaminate the food chain.

nylon cnc machining

Advantages and Limitations of Nylon

The following are the benefits and limitations of Nylon in detail.

Advantages of Nylon

  1. Wear Resistance: It is low friction and abrasion resistant. Therefore used in components that move past one another.
  2. Lightweight: It has Low density, which means that it is ideal for weight-conscious devices and equipment.
  3. Versatility in Manufacturing: Low compounding and processing temperature and can be easily extruded, machined, and also recyclable.

Limitations of Nylon

  • Moisture Absorption: It Absorbs moisture that causes changes in dimensions and deterioration in the physical and mechanical properties.
  • Hydrolysis Sensitivity: Hydrolytically unstable at high temperatures and where the relative humidity is high.
  • Thermal Limitations: Melting range of 220-270°C with possible thermal decay of product.
  • Chemical Sensitivity: It shows no notable stability in strong acids and bases.

Key Considerations for Nylon Safety

Here are two main considerations, we should keep in mind regarding nylon; such as

1. Temperature Sensitivity

Generally, nylon is a very stable material. However, when subjected to high temperatures it will decompose. However, for high-temperature exposure, nylon may begin to degrade and give off poisonous products like ammonia products, hydrogen cyanide, and carbon monoxide. Thus, nylon should only be used to temperatures as recommended for each type of nylon, which should not go over about 180°C (356°F). So, we can reduce the risk of fire and burn.

2. Hydrolysis

Yes, nylons are sensitive to hydrolysis, which is a reaction to water that makes the polymer chains degrade. This is more likely to happen especially if the surrounding air is damped with high humidity and or high temperatures. Hydrolysis can be parasitic to the mechanical characteristics of nylon. So, it can cause emissions of degradation products. In the cases where nylon is used under conditions of contact with moisture and heat. It could be affected by hydrolysis. So, it is necessary to choose the grades of nylon that are less sensitive to this process.

Conclusion:

To sum up, nylon is a tough and durable material. We have discussed the various safety and environmental impacts of nylon. Nylon is safe to produce molded parts. It is also safe for food contact. But there are certain risks associated with it. Health safety risks include skin and eye irritation, digestive issues, and potential cancer and neurological disorders. Environmental safety concerns include high energy consumption and pollution. Overall, nylon is considered safe for use in everyday life. But,  care should be taken when using it under specific conditions, such as high temperatures. Additionally, it is advisable to choose sustainable and environmentally friendly product options.

Frequently Asked Questions

Q1. What are the main areas of application of nylon plastic?

Nylon plastic is used in many industries such as the automotive industry in parts manufacture, and the electric industry for devices manufacturing. Besides this, it is used in the manufacture of fabrics fashion accessories, manufacture of industrial machine parts, among others.

Q2. Is nylon plastic safe for food applications and medical products?

Yes, there are nylon grades that are FDA-compliant for food applications and are used in food packaging, food handling tools, and food processing equipment. Nylon also finds its use in the medical field, since it is biocompatible and highly stable.

Q3. Is it possible to recycle nylon?

Yes, nylon is among the fully recyclable materials and can be reused by being processed again for the production of new products.

 

injection molding wall thickness

Information about PA6/PA66 (Nylon) Injection Molding

Basically, there are PA6 AND PA66(Nylon 6 or Nylon 66), Nylon has tenacious and wearable,  self-lubricious and smooth characteristics with non-toxic and antibiosis and high water absorbability. In addition, its tensile strength and stiffness will be sharply decreased with the moisture-absorbing. Then, the size of finished pieces changes greatly. If in the high-temperature environment for a long time, it will be resolved.

It will not soften gradually with increasing high temperature until closing to the extent of melting-point. Once reaching the proper temperature, it will flow. It is soluble in many chemicals. However, gas, lubricating oil, developer, detergent and grease have no effect on nylon.

Nylon injection molding

Advantages Nylon Injection Molding :

It has high mechanical strength, good tenacity and high press resistance and strength of extension. Its strength of extension is close to yielding strength, which is twice stronger than ABS injection molding parts.

Nylon Injection molding parts have excellent fatigue durability with the smooth surface and minor friction coefficient and good wear resistance. It also has corrosion resistance and remarkable resistance to alkali (acid) and most of the salt solution, non-toxic, presenting inertia to biological erosion and good anti-mildew ability, heat resistance and excellent electrical features.

Its product has a lightweight and is easy to dye and molding.

Disadvantages of PA injection molding:

It is easy to absorb water and has poor light resistance. It requires more strict plastic molding technology. It can absorb water and becomes swelling in alcohol but has no resistance to strong acid and oxidizer.

Therefore, it cannot be used as acid-resisting material.

Nylon Injection Molding process:

We should exactly control the injection molding process to prevent problems like flashing. Meanwhile, as the faster speed of condensation quick releasing for melt, we should keep off the insufficient production caused by material blocking in orifice runner and gate (temperature and pressure increase liquidity firstly).

As the poor thermal stability, the temperature should not be too high so as not to cause yellowing of material.

The proper injection pressure can be judged by the appearance of the products. If it has higher injection pressure, products will appear the problems such as flashing; the too low temperature will bring about defects like a ripple, flow mark, weld line or insufficient producing. Therefore, the higher holding pressure should be avoided in order to prevent increasing the internal stress for products generally.

It is advisable that injection should be done with speed so as to avoid problems such as ripple or insufficient mold filling caused by the rapid cooling rate.

PA Nylon injection molding Technique

1, Preparation of Original Materials
PA (polyamides) absorbs humidity easily, which has an effect on the course of working, like decreasing viscosity of the melt and appearing bubbles and crazing on the surface, etc. And force property of product will also decrease obviously. Therefore, the drying process must be done before shaping up. Besides, PA is easily oxidized and color changed as well as decomposition under hot temperature, so it will be better with vacuum drying. But if there is no vacuum drying condition, atmospheric hot air drying can also be adopted.

The temperature of vacuum drying is 85-95 Celsius degrees and the lasting time is 4-6H; while the temperature of hot air drying is 90-100 Celsius degrees and the lasting time is 8-10H. PA materials after being dried are not fit for locating in the air (not more than 1-3H).

2, Melting Temperature
The choice of the machine barrel is mainly based on the melting point of PA Material. At the same time, it is also related to the type of injection molding machine, type of product and size. Generally, under 220-320 Celsius degrees, PA6: 220-300 Celsius degrees; PA66: 260-320 Celsius degrees, as the processing temperature of PA is narrow, so the temperature of machine barrel must be controlled strictly, in order to avoid decomposition of melt thus to make the product go bad. The setting of the machine barrel has a large effect on plasticizing and speed of melt.

The temperature of the middle section of the machine barrel should be higher than the melting point of 20–40 Celsius degrees and lower than the decomposition of 20-30 Celsius degrees. The temperature of the front section is lower than the middle section of 5-10 Celsius degrees. The temperature of back-end (loading section) is lower than the middle section of 20-50 Celsius degrees. Cooling of the charging hole must be effective. If the temperature of the middle section is too low and the screw changes its speed too fast, then jamming phenomenon will appear. If the temperature of the posterior section is too high, then the delivering capacity will be affected. A lower speed of screw will affect production efficiency.

3, Injection Pressure
Injection pressure has a small effect on the force of PA. Choosing of injection pressure mainly depends on the type of injection molding machine, machine barrel temperature, type and size of the product, and mold structure. And there are also some factors like injection speed, injection time and injection time, etc.

4, Injection Speed
Choosing of injection speed is related to the thickness of the product, the temperature of the melt, the size of the gate, etc. The injection speed cannot be so fast. Otherwise, the excess temperature will be caused due to over cutting thus to create decomposition, causing color changing of product and decrease of force property. Too fast injection speed will also create defects like bubble and scorching, etc.

5, Revolving Speed of Screw
Intermediate speed should be adopted. The too-fast speed may cause decomposition of plastic due to excessive cutting, causing color changing and decrease of property and too slow of revolving speed, which may affect the quality of melt and production efficiency due to a long period of melting.

6, Back-pressure
On the premise to guarantee the quality of the product that the lower of the back-pressure is the better. High back-pressure may decompose due to the excessive cutting of melting.

hdpe injection molding

7, Mold temperature for PA injection molding

The high temperature of mold improves hardness, density, tensile strength and modulus of elasticity of the product. Mold temperature is related to the property of the product. As to those thin products which require elongation and good transparency, it will be better with lower mold temperature; while as to those thick molds which require high strength, good abrasion resistance and transformation less, and then higher temperature of mold temperature is better. The specific is as follows.

The thickness of product temperature of mold: Less than 3mm, mold temperature use 50 -70 Celsius degrees, 3-6mm, mold temperature use 70-90 Celsius degrees, 6-10mm, mold temperature use 80-100 Celsius degrees, and wall thickness is more than 10mm, 100 Celsius degrees Mold temperature has a big effect on contractibility rate of product. The higher of the mold temperature, the bigger of the contractibility, otherwise, the smaller of the contractibility rate.

8, Molding Cycle
It mainly depends on the thickness of the product. As to thin wall product, the injection time, pressure maintaining time and cooling time can all be shorter; while as for thick wall product, in order to avoid the appearance like shrinkage transformation, sink mark and bubbles, etc., then injection time and pressure maintaining time should be lengthened and high mold temperature should be adopted. The cooling time should be longer.

9, Post-processing of Product
Crystallization of the process of molecular orientation and cooling process while in the process of cooling creates some internal stress in the product. The size and shape of the product will change while in the future storage and using process. Therefore, annealing and humidifying processing are required.

10, Annealing
It adopts a product that is 80 Celsius degrees higher of the temperature and accurate precision. The product is taken out after being demoulded, putting in oil or paraffin for annealing. The temperature of annealing is higher than the usage temperature of 10-20 Celsius degrees and time is 10-60 minutes. (Depending on the thickness of product)

11, Humidifying
While in the process of shaping up, a product that is used in humanity or aqueous solution must be put into boiling water or potassium acetate solution for 1-2 days after taken out.

12, Residence Time
While in the process of manufacturing, if the temperature of glue is above 300 Celsius degrees, then the long residence time of melting in the machine barrel must be avoided (20 minutes), otherwise decomposition will be caused due to overheating, causing the color change of product or brittleness. If a temporary stoppage for more than 20 minutes is required, then the temperature of the machine barrel can be lowered to 200 Celsius degrees. When in a long time of residence, polymer with higher viscosity must be used to clean the machine barrel. For example, HDPE or PP can be used for cleaning.

Contact us to get a price for your PA injection molding (PA6, PA66, PA12) or any other custom injection molding projects.